Journal of the Chemical Society, Dalton Transactions p. 3459 - 3464 (1994)
Update date:2022-08-05
Topics:
Cao, Rong
Hong, Maochun
Jiang, Feilong
Xie, Xiulan
Liu, Hanqin
The reactions of Ni(2+), edt(2-) and PR3 (R = Ph or Et) in MeOH gave the complexes a = 14.086(4), b = 25.569(11), c = 13.768(4) Angstroem, Z = 8, R = 0.060.Complex 4 also crystallizes in the orthorhombic space group Pbca with a = 10.935(8), b = 28.826(15), c = 9.437(4) Angstroem, Z = 8, R = 0.047.All the nickel atoms are four-co-ordinated with distorted square-planar geometries of phosphorus and/or sulfur atoms.In the reaction system condensation of edt(2-) occurs through a C-S bond disruption to form tpdt(2-), which co-ordinates to the nickel atoms to give complexes 1 and 4.
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