Reactions of Spirohept-4-ene Derivatives with Tetracyanoethylene. Extensive Rearrangements Involving the Aza-Cope Process

DOI: 10.1021/jo00043a024

Source and publish data:

Journal of Organic Chemistry p. 4658 - 4663 (1992)

Update date:2022-09-26

Topics:

Authors:

Nishida, Shinya

Asanuma, Naoki

Murakami, Masashi

Tsuji, Takashi

Imai, Toshiro

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Article abstract of DOI:10.1021/jo00043a024

In CH2Cl2 or CH3CN, 1,1-dicyclopropylspiro<2.4>hept-4-ene (4a) reacted readily with TCNE in a unique manner to give 4--6-methylenebicyclo<3.3.0>oct-3-ene-2,2,3-tricarbonitrile (8a), an imine after extensive rearrangements,

Full text of DOI:10.1021/jo00043a024

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