An Efficient Synthesis of 1,3-Cyclohexadienes from Oxabicycloheptenes via Tandem Ring Opening-Peterson Elimination Reactions

DOI: 10.1021/jo00041a003

Source and publish data:

Journal of Organic Chemistry p. 4065 - 4066 (1992)

Update date:2022-09-26

Topics:

Authors:

Lautens, Mark

Ma, Shihong

Belter, Randolph K.

Chiu, Pauline

Leschziner, Andres

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00041a003

Oxabicyclo<2.2.1>heptenes react with PhMe2SiLi or PhMe2SiCu*LiCN to yield 1,3-cyclohexadienes.The reaction pathway is shown to proceed via an addition-elimination-Peterson olefination sequence.

Full text of DOI:10.1021/jo00041a003

Products guided by the article

Product name:(2-Methyl-cyclohexa-2,4-dienyl)-methanol

Cas No:142634-54-6

R&D Labs maybe for 142634-54-6

Du-Hope International Group

website:http://www.np-chem.com

Contact:0086-25-52346877

Address:199, Jian Ye Road, Nanjing, China
HANGZHOU ICH BIOFARM CO.,LTD

Contact:+86-571-28186845

Address:Room 1224,Eastcom Mansion,398 Wensan Road,Hangzhou,310013 China
Guangzhou Swan Chemical Co., Ltd.

Contact:+86-20-31075659

Address:NO.301, Hong ba fang investment BLDG 1,Guan chong village,Shiqi town,Panyu district,Guangzhou
TAIZHOU XINGCHENG CHEMPHARM CO.,LTD.

Contact:0086-0576-88551200,88886292 ,88880039

Address:B Area. 10 Floor.Yaodadasha. 289#.Shifu Road.Taizhou.Zhejiang.China
Chengdu NoVi Biotechnology Co., Ltd.(expird)

Contact:13551243286/028-81458053

Address:NO.168-1-224 JULONG ROAD WUHOU DISTRICT, CHENGDU CITY,SICHUAN PROVINCE

Relevant to this article

A convenient synthesis of 5-substituted 2-amino-1,3,4-oxadiazoles from corresponding acylthiosemicarbazides using iodine and Oxone

Doi:10.3184/174751912X13551638283701
(2013)
Partial Synthesis of 9,10-Syn Diterpenes via Tosylhydrazone Reduction: (-)-(9β)-Pimara-7,15-diene and (-)-(9β)-Isopimaradiene

Doi:10.1021/jo00043a013
(1992)
Chemo-enzymatic synthesis and glycosidase inhibitory properties of DAB and LAB derivatives

Doi:10.1039/c3ob27343a
(2013)
Novel mixed-heteroatom macrocycles via templating: A new protocol

Doi:10.1016/j.tetlet.2013.01.025
(2013)
Synthesis of biotin linkers with the activated triple bond donor [p-(N-propynoylamino)toluic Acid] (PATA) for efficient biotinylation of peptides and oligonucleotides

Doi:10.3390/molecules171214174
(2012)
Synthesis of phthalazinones via palladium(ii)-catalysed intramolecular oxidative C-H/C-H cross-coupling of N′-methylenebenzohydrazides

Doi:10.1039/c3ob40195b
(2013)

Article Doi