An Efficient Synthesis of 1,3-Cyclohexadienes from Oxabicycloheptenes via Tandem Ring Opening-Peterson Elimination Reactions

DOI: 10.1021/jo00041a003

Source and publish data:

Journal of Organic Chemistry p. 4065 - 4066 (1992)

Update date:2022-09-26

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Authors:

Lautens, Mark

Ma, Shihong

Belter, Randolph K.

Chiu, Pauline

Leschziner, Andres

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Article abstract of DOI:10.1021/jo00041a003

Oxabicyclo<2.2.1>heptenes react with PhMe2SiLi or PhMe2SiCu*LiCN to yield 1,3-cyclohexadienes.The reaction pathway is shown to proceed via an addition-elimination-Peterson olefination sequence.

Full text of DOI:10.1021/jo00041a003

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