Rhodium-catalyzed conversion of furans to highly functionalized pyrroles

DOI: 10.1021/ja401386z

Source and publish data:

Journal of the American Chemical Society p. 4716 - 4718 (2013)

Update date:2022-08-05

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Authors:

Parr, Brendan T.

Green, Samantha A.

Davies, Huw M. L.

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Article abstract of DOI:10.1021/ja401386z

The synthesis of highly functionalized pyrroles has been achieved by reaction of rhodium-stabilized imino-carbenes with furans. The reaction features an initial [3+2] annulation to form bicyclic hemiaminals, followed by ring opening to generate trisubstituted pyrroles.

Full text of DOI:10.1021/ja401386z

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