Total Synthesis of (+)-9,10-syn- and (+)-9,10-anti-Copalol via Epoxy Trienylsilane Cyclizations

DOI: 10.1021/jo00043a014

Source and publish data:

Journal of Organic Chemistry p. 4598 - 4608 (1992)

Update date:2022-07-30

Topics:

Authors:

Yee, Nathan K. N.

Coates, Robert M.

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Article abstract of DOI:10.1021/jo00043a014

Total syntheses of (+)-9,10-syn-copalol (5), the pyrophosphate ester of which is a likely intermediate in the biosynthesis of 9,10-syn diterpenes, and its 9,10-anti isomer 39 are reported.Lithiation of (-)-(6R)-6,7-epoxygeranyl p-tolylsulfone (-)-19 or (+

Full text of DOI:10.1021/jo00043a014

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