Total Synthesis of (+)-9,10-syn- and (+)-9,10-anti-Copalol via Epoxy Trienylsilane Cyclizations

DOI: 10.1021/jo00043a014

Source and publish data:

Journal of Organic Chemistry p. 4598 - 4608 (1992)

Update date:2022-07-30

Topics:

Authors:

Yee, Nathan K. N.

Coates, Robert M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00043a014

Total syntheses of (+)-9,10-syn-copalol (5), the pyrophosphate ester of which is a likely intermediate in the biosynthesis of 9,10-syn diterpenes, and its 9,10-anti isomer 39 are reported.Lithiation of (-)-(6R)-6,7-epoxygeranyl p-tolylsulfone (-)-19 or (+

Full text of DOI:10.1021/jo00043a014

Products guided by the article

Product name:2,6-Octadienoic acid, 6-methyl-8-(phenylmethoxy)-2-[(trimethylsilyl)methyl]-, ethyl ester, (E,E)-

Cas No:142720-30-7

R&D Labs maybe for 142720-30-7

JiangXi Hong Run Chemical Co., Ltd

Contact:+86-0791-88521351

Address:XingHuo industrial zone in YongXiu county
SuZhou Bichal Biological Technology CO.,LTD

Contact:+86-512-68051130

Address:NO.32 huoju road HI-TECH Industrial development zone SuZhou China
Chengdu Boon Stream Chemical Industry Co.,Ltd.

Contact:+86-28-83156758

Address:No.859,Dongzikou Road,Jinniu District,Chengdu,Sichuan,P.R.China
Luzhou North Chemical Co., Ltd.

Contact:+86-830-2796784；+86-830-2796776

Address:Gaoba, Longmatan District, Luzhou, Sichuan Province
Lishui Nanming Chemical Co., Ltd(expird)

Contact:+86-0578-2134101，2697830

Address:No.19 Tongji Road Shuige Industrial zone

Relevant to this article

Synthesis of Di- and Triarylmethanes through Palladium-Catalyzed Reductive Coupling of N -Tosylhydrazones and Aryl Bromides

Doi:10.1055/s-0036-1588893
(2017)
1-(Benzenesulfonyl)- and 1-(p-Toluenesulfonyl)-3-methylimidazolium Triflates: Efficient Reagents for the Preparation of Arylsulfonamides and Arylsulfonates

Doi:10.1021/jo00043a046
(1992)
Structure activity relationships of human galactokinase inhibitors

Doi:10.1016/j.bmcl.2014.11.061
(2015)
Facile one pot multicomponent synthesis of novel 4-(benzofuran-2-yl)-2-(3-(aryl/heteryl)-5-(aryl/heteryl)-4,5-dihydro-1H-pyrazol-1yl)thiazole derivatives

Doi:10.1080/00397911.2018.1440600
(2018)
Chemistry and pharmacological studies of 3-alkoxy-2,5-disubstituted- pyridinyl compounds as novel selective α4β2 nicotinic acetylcholine receptor ligands that reduce alcohol intake in rats

Doi:10.1021/jm4000374
(2013)
Synthesis, characterization and hplc analysis of the (1S,2S,5R)-diastereomer and the enantiomer of the clinical candidate ar-15512

Doi:10.3390/molecules26040906
(2021)

Article Doi