Allylsilanes in Organic Synthesis; Double Asymmetric Induction in the Dihydroxylation of a Chiral Allylsilane.

DOI: 10.1016/0040-4020(95)00736-R

Source and publish data:

Tetrahedron p. 12821 - 12836 (1995)

Update date:2022-08-04

Topics:

Authors:

Ward, Richard A.

Procter, Garry

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Article abstract of DOI:10.1016/0040-4020(95)00736-R

The diastereoselectivity of the dihydroxylation of ester-allylsilanes, particularly stereoisomers of methyl E-2-methyl-3-(phenyldimethylsilyl)hept-4-enoate, has been studied; the diastereoselectivity can be increased by using potassium ferricyanide as the

Full text of DOI:10.1016/0040-4020(95)00736-R

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