Unexpected C3 arylation of 3,4,6-tri-O-methyl-2-C-formylglycals: A simple route to 3-C-arylhexoses

DOI: 10.1016/S0040-4039(00)79597-9

Source and publish data:

Tetrahedron Letters p. 3049 - 3052 (1992)

Update date:2022-08-03

Topics:

Authors:

Booma Booma

Balasubramanian

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)79597-9

Unusual regiochemistry in the nucleophilic reaction of substituted 2-C-formylglycals with phenols under Lewis acid catalysis leading to 3-C-arylhexoses is reported.

Full text of DOI:10.1016/S0040-4039(00)79597-9

Products guided by the article

Product name:(4S,5R,6R)-4-(2-Hydroxy-5-methoxy-phenyl)-5-methoxy-6-methoxymethyl-5,6-dihydro-4H-pyran-3-carbaldehyde

Cas No:142822-40-0

R&D Labs maybe for 142822-40-0

xuri chemicals co., ltd

Contact:86-516-66656369

Address:The west road of Huaihai, Xuzhou, China
LIANYUNGANG YC FINE CHEMICAL CO., LTD

Contact:+86-518-858 99188

Address:Shangdong Modern Bldg, South Greenpark Road, Lianyungang, Jiangsu Pro. China
Xinji City Taida Sinopec Co., Ltd.

Contact:0086-311-85341278

Address:No.6, Nanhua Road,Xinji City Road,Hebei Province,China
Hubei Xinghuo Chemical Co., Ltd.,

Contact:13925817279 13907299441

Address:Xinghuo Fine Chemistry Industrial Park, Xiaochang County, Hubei Province, China
Jiangsu Allyrise Pharmaceutical Co., Ltd.(expird)

Contact:+86-523-86818997

Address:Taizhou,Jiangsu Province,CHINA

Relevant to this article

Physicochemical studies and biological evaluation on (E)-3-(2-(1-(2- hydroxyphenyl)hydrazinyl)-3-oxo-N-(thiazol-2yl)propanamide complexes

Doi:10.1016/j.saa.2013.01.031
(2013)
Sc(OTf)₃-catalyzed dehydrogenative cyclization for synthesis of N-methylacridones

Doi:10.1021/ol400371h
(2013)
Synthetic studies of carzinophilin. Part 1: Synthesis of 2-methylidene-1-azabicyclo[3.1.0]hexane systems related to carzinophilin

Doi:10.1016/S0040-4020(03)00377-6
(2003)
Synthesis of Swinhoeisterol A, Dankasterone A and B, and Periconiastone A by Radical Framework Reconstruction

Doi:10.1021/jacs.9b12899
(2020)
Hypervalent iodine in synthesis; 5. The reaction between diaryliodonium salts and thiocarboxylic acid salts: A convenient method for the synthesis of S-aryl thiocarboxylates

Doi:10.1055/s-1992-26150
(1992)
Benzannulation of 2-Alkenylindoles using Aldehydes by Sequential Triple-Relay Catalysis: A Route to Carbazoles and Carbazole Alkaloids

Doi:10.1002/adsc.201700092
(2017)

Article Doi