Unexpected C3 arylation of 3,4,6-tri-O-methyl-2-C-formylglycals: A simple route to 3-C-arylhexoses

DOI: 10.1016/S0040-4039(00)79597-9

Source and publish data:

Tetrahedron Letters p. 3049 - 3052 (1992)

Update date:2022-08-03

Topics:

Authors:

Booma Booma

Balasubramanian

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)79597-9

Unusual regiochemistry in the nucleophilic reaction of substituted 2-C-formylglycals with phenols under Lewis acid catalysis leading to 3-C-arylhexoses is reported.

Full text of DOI:10.1016/S0040-4039(00)79597-9

Products guided by the article

Product name:(4S,5R,6R)-4-(2-Hydroxy-5-methoxy-phenyl)-5-methoxy-6-methoxymethyl-5,6-dihydro-4H-pyran-3-carbaldehyde

Cas No:142822-40-0

R&D Labs maybe for 142822-40-0

Chinapeptides Co,. Ltd

Contact:+86-021-50792271

Address:Building 24A, 300 Chuantu Road, Chuansha, Pudong new area, Shanghai, China, 201202
SuZhou Ascepion Pharmaceuticals, Inc.(expird)

Contact:0512-86881668

Address:Building C,68Xingqing Road,Suzhou,China.
shanghai jiuling chemical co.,ltd.

Contact:+86-21-50387295

Address:Zaozhuang Road, Pudong, Shanghai City. China
Longhui qunfeng Chemical Co., Ltd

Contact:86-731-82173407

Address:South-east Industrial Park, Longhui County, Hunan Province, China
WUXI HONOR SHINE CHEMICAL CO.,LTD

Contact:+86-510-83593312

Address:No.1699 Huishan avenue,Huishan district,Wuxi ,Jiangsu,China,214177.(Wuxi Huishan Ecomonic Develop Zone )

Relevant to this article

Physicochemical studies and biological evaluation on (E)-3-(2-(1-(2- hydroxyphenyl)hydrazinyl)-3-oxo-N-(thiazol-2yl)propanamide complexes

Doi:10.1016/j.saa.2013.01.031
(2013)
Sc(OTf)₃-catalyzed dehydrogenative cyclization for synthesis of N-methylacridones

Doi:10.1021/ol400371h
(2013)
Synthetic studies of carzinophilin. Part 1: Synthesis of 2-methylidene-1-azabicyclo[3.1.0]hexane systems related to carzinophilin

Doi:10.1016/S0040-4020(03)00377-6
(2003)
Synthesis of Swinhoeisterol A, Dankasterone A and B, and Periconiastone A by Radical Framework Reconstruction

Doi:10.1021/jacs.9b12899
(2020)
Hypervalent iodine in synthesis; 5. The reaction between diaryliodonium salts and thiocarboxylic acid salts: A convenient method for the synthesis of S-aryl thiocarboxylates

Doi:10.1055/s-1992-26150
(1992)
Benzannulation of 2-Alkenylindoles using Aldehydes by Sequential Triple-Relay Catalysis: A Route to Carbazoles and Carbazole Alkaloids

Doi:10.1002/adsc.201700092
(2017)

Article Doi