Substituent-dependent reactivity in aldehyde transformations: 4-(phenylethynyl)benzaldehydes versus simple benzaldehydes

DOI: 10.1016/j.tet.2013.03.056

Source and publish data:

Tetrahedron p. 4098 - 4104 (2013)

Update date:2022-08-04

Topics:

Authors:

Katsuyama, Isamu

Chouthaiwale, Pandurang V.

Cui, Hai-Lei

Ito, Yuji

Sando, Ayumi

Tokiwa, Hiroaki

Tanaka, Fujie

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/j.tet.2013.03.056

Effects of substituents on transformations of 4-(phenylethynyl) benzaldehydes and related benzaldehydes were analyzed in aldol and thiazolidine formation reactions. The aldol reaction of 4-cyanobenzaldehyde was 54-fold faster than that of 4-methoxybenzald

Full text of DOI:10.1016/j.tet.2013.03.056

Products guided by the article

Product name:4-hydroxy-4-(4-(4-trifluoromethylphenylethynyl)phenyl)butan-2-one

Cas No:1430415-27-2

R&D Labs maybe for 1430415-27-2

SPRING CHEMICAL INDUSTRY CO.,LTD

Contact:86-187-66672125

Address:linchi industry park.zouping
Jiangsu Haian Petro chemical Plant

Contact:+86-513-88902723

Address:99, Changjiang West Road, Haian County, Jiangsu
Jiangxi Dongbang Pharmaceutical Co., Ltd.

Contact:+86-795-4433603, 4433388

Address:Fengxin Industrial Park, Fengxin County, Jiangxi Province, P.R.C
Hangzhou Mole's Science & Technology Co.,Ltd.(expird)

Contact:+86-571-56880228

Address:15F Guodu development Building, NO.182 Zhaohui Road
Nanjing Yuance Industry&Trade Co., Ltd.

website:http://www.njyuance.cn/

Contact:+86-25-85439097

Address:B1702, Aoti Bldg, No. 130, Aoti Avenue, Nanjing, China

Relevant to this article

Next generation photoCORMs: Polynuclear tricarbonylmanganese(I)- functionalized polypyridyl metallodendrimers

Doi:10.1021/ic400377k
(2013)
Iron(III)-catalyzed dehydration C(sp²)-C(sp²) coupling of tertiary pro-pargyl alcohols and α-oxo ketene dithioacetals: A new route to gem -bis(alkylthio)-substituted vinylallenes

Doi:10.1055/s-0032-1316855
(2013)
Silver-catalyzed enantioselective desymmetrization: Facile access to spirolactone-pyrrolidines containing a spiro quaternary stereogenic center

Doi:10.1021/ol400821q
(2013)
Synthesis of a bipyridine-derived achiral thiourea trifluoromethanesulfonic acid salt and its application as an additive in organocatalytic asymmetric reactions

Doi:10.1016/j.tetlet.2013.08.004
(2013)
Design and synthesis of 1-aryl-5-anilinoindazoles as c-Jun N-terminal kinase inhibitors

Doi:10.1016/j.bmcl.2013.02.082
(2013)
Catalyst-free Mannich reaction of hydroxyanthraquinone: Facile access to emodin Mannich bases and anthraoxazines

Doi:10.1016/j.tetlet.2013.03.059
(2013)

Article Doi