Alkylation of the (η4-Cyclohexa-1,3-diene)(η5-cyclopentadienyl)(dicarbonyl)molybdenum Hexafluorophosphate with the Highly Functionalized Zinc-Copper Reagents RCu(CN)ZnI

DOI: 10.1039/c39920000890

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 890 - 891 (1992)

Update date:2022-08-04

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Authors:

Yeh, Ming-Chang P.

Tsou, Chung-Jy

Chuang, Chong-Nan

Lin, Hwei-Chi

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Article abstract of DOI:10.1039/c39920000890

The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)ZnI to the title cation at the terminus of the coordinated diene ligand gives (Cp = cyclopentadienyl) complexes with the functionalized side-chain at the C-4 position of the ring: intramolecular cyclisation of the (?-allyl)molybdenum complex 4 containing a pendant propanoic acid unit generates the δ-lactone derivative 6.

Full text of DOI:10.1039/c39920000890

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