Alkylation of the (η4-Cyclohexa-1,3-diene)(η5-cyclopentadienyl)(dicarbonyl)molybdenum Hexafluorophosphate with the Highly Functionalized Zinc-Copper Reagents RCu(CN)ZnI

DOI: 10.1039/c39920000890

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 890 - 891 (1992)

Update date:2022-08-04

Topics:

Authors:

Yeh, Ming-Chang P.

Tsou, Chung-Jy

Chuang, Chong-Nan

Lin, Hwei-Chi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920000890

The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)ZnI to the title cation at the terminus of the coordinated diene ligand gives (Cp = cyclopentadienyl) complexes with the functionalized side-chain at the C-4 position of the ring: intramolecular cyclisation of the (?-allyl)molybdenum complex 4 containing a pendant propanoic acid unit generates the δ-lactone derivative 6.

Full text of DOI:10.1039/c39920000890

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2-Cyclohexene-1-butanoic acid, 4-(phenylthio)-, ethyl ester, trans-

Cas No:143052-01-1

R&D Labs maybe for 143052-01-1

Hangzhou Neway Chemicals Co., Ltd.

Contact:+86-571-85095566

Address:Room 803, Qinglian Bldg, No 139 Qingchun Road, Hangzhou, Zhejiang China
Tianjin Boron PharmaTech Co.,Ltd.(expird)

Contact:86-022-59845187

Address:B9-401, Tianda Science Park,No.80,4th Avenue,TEDA,Tianjin, China
Hangzhou Yingshanhua Pigment Chemicals Co.,Ltd.

Contact:+86-0150-58101658

Address:Nanyang Economic DevelopmentZong,Xiaoshan,Hangzhou,China
Dezhou Longteng Chemical Co., Ltd.

website:http://www.sodium-methoxide.cn/

Contact:0086-18866052283

Address:Xinhua Industrial Zone, Dezhou City, Shandong Province, China
Disynthesis Chemical Technology Co. Ltd.

Contact:+86-571-88194596

Address:Dengyun road 380, Gongshu district, Hangzhou city, China

Relevant to this article

Discovery of a new class of highly potent inhibitors of acid ceramidase: Synthesis and structure-activity relationship (SAR)

Doi:10.1021/jm301879g
(2013)
Oligo(p-phenyleneethynylene)-functionalized perylenebisimidetriad: Synthesis, photophysical properties, and self-assembly

Doi:10.1002/cjoc.201200858
(2013)
Tuning the bioactivity of tensioactive deoxy glycosides to structure: Antibacterial activity versus selective cholinesterase inhibition rationalized by molecular docking

Doi:10.1002/ejoc.201201520
(2013)
Synthesis of new heterocyclic hybrids based on pyrazole and thiazolidinone scaffolds as potent inhibitors of tyrosinase

Doi:10.1016/j.bmc.2012.12.053
(2013)
Selective synthesis of oxygen-containing heterocycles via tandem reactions of 1,2-allenic ketones with ethyl 4-chloroacetoacetate

Doi:10.1039/c3ra23432k
(2013)
Doi:10.1021/jo00956a008
(1973)

Article Doi