Diols obtained via chemo and regioselective ring opening of epoxy alcohols: A straightforward synthesis of 2S,3S-octandiol

DOI: 10.1016/S0040-4020(01)92240-9

Source and publish data:

Tetrahedron p. 1531 - 1538 (1992)

Update date:2022-09-26

Topics:

Authors:

Bonini, Carlo

Righi, Giuliana

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Article abstract of DOI:10.1016/S0040-4020(01)92240-9

Epoxy alcohols are regio and chemoselectively opened to the corresponding iodohydrins and then reduced in situ to diols; the application of the described procedure leads to a short asymmetric of a well known pheromone. Also homoallylic (E and Z) epoxy alcohols and its benzylated derivatives shows high preference for regioselective opening affording the corresponding 1,3 diol.

Full text of DOI:10.1016/S0040-4020(01)92240-9

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