Synthesis of Phorbol C-Ring Analogs: A Biomimetic Model Study on the Phorbol to 12-Hydroxydaphnetoxin Conversion

DOI: 10.1021/jo00046a017

Source and publish data:

Journal of Organic Chemistry p. 5360 - 5369 (1992)

Update date:2022-08-05

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Authors:

Magar, Sharad S.

Desai, R. C.

Fuchs, P. L.

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Article abstract of DOI:10.1021/jo00046a017

An eight-step synthesis of phorbol C-ring analogs is described.The results of a model study on the phorbol to 12-hydroxydaphnetoxin biomimetic conversion using a C-9 ester-assisted cyclopropyl carbinyl rearrangement are presented.Under the basic condition

Full text of DOI:10.1021/jo00046a017

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