Journal of Organic Chemistry p. 5058 - 5060 (1992)
Update date:2022-09-26
Topics:
Meyer, Stephanie D.
Miwa, Tetsuo
Nakatsuka, Masashi
Schreiber, Stuart L.
Phosphine oxide 2, representing the C10-C21 portion of rapamycin, was stereoselectively synthesized and was demonstrated to undergo a Horner-Wittig reaction to form triene 25 as an 8:1 mixture of trans-cis isomers.
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Doi:10.1016/S0040-4039(00)74703-4
(1992)Doi:10.1016/S0040-4039(00)60995-4
(1992)Doi:10.1039/c1ob05871a
(2011)Doi:10.1002/anie.201105020
(2011)Doi:10.1016/j.jorganchem.2014.10.002
(2014)Doi:10.1021/ja200231v
(2011)
