Tetrahedron Letters p. 3833 - 3836 (1992)
Update date:2022-08-05
Topics: Catalyst Enantioselectivity Alkene Alkyne Asymmetric Dihydroxylation Enynes
Jeong, Kyu-Sung
Sjoe, Peter
Sharpless, K. Barry
Catalytic asymmetric dihydroxylations of 1,3-enynes were studied using 9-0-(9′-phenanthryl) dihydroquinidine (PHN-DHQD) 1 and 1,4-bis-(9-0-dihydroquinidine) phthalazine (DHQD2-PHAL) 2. Terminal olefins showed moderate (38-79% ee) and trans-disu
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