A Selenurane Derivative Promotes β-Fragmentation of Carbinolamides Leading to Cyclic Imides

DOI: 10.1016/S0040-4039(00)79971-0

Source and publish data:

Tetrahedron Letters p. 1083 - 1086 (1994)

Update date:2022-08-04

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Authors:

Dorta, Rosa L.

Francisco, Cosme G.

Suarez, Ernesto

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Article abstract of DOI:10.1016/S0040-4039(00)79971-0

The alkoxy radical intermediates generated by reaction of carbinolamides with diphenylselenium hydroxyacetate (1) in the presence of iodine and under irradiation with visible light undergo β-fragmentation to afford 3,4-substituted cyclic imides in good yields.

Full text of DOI:10.1016/S0040-4039(00)79971-0

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