Diastereoselective Addition of Metal-coordinated and 'Naked' Tri-sec-butylborohydrides to a Norephedrine-derived 2-Acetyloxazolidine

DOI: 10.1039/c39920001027

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1027 - 1029 (1992)

Update date:2022-08-05

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Authors:

Manzoni, Leonardo

Pilati, Tullio

Poli, Giovanni

Scolastico, Carlo

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Article abstract of DOI:10.1039/c39920001027

The addition of tri-sec-butylborohydrides to the 2-acetyl-1,3-oxazolidine 1 can be directed with high selectivity to either the Si or the Re ?-carbonyl face under chelating or non-coordinating conditions, respectively.

Full text of DOI:10.1039/c39920001027

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