Diastereoselective Addition of Metal-coordinated and 'Naked' Tri-sec-butylborohydrides to a Norephedrine-derived 2-Acetyloxazolidine

DOI: 10.1039/c39920001027

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1027 - 1029 (1992)

Update date:2022-08-05

Topics:

Authors:

Manzoni, Leonardo

Pilati, Tullio

Poli, Giovanni

Scolastico, Carlo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920001027

The addition of tri-sec-butylborohydrides to the 2-acetyl-1,3-oxazolidine 1 can be directed with high selectivity to either the Si or the Re ?-carbonyl face under chelating or non-coordinating conditions, respectively.

Full text of DOI:10.1039/c39920001027

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(1R,2'S,4'S,5'R)-1-<4'-methyl-5'-phenyl-3'-(toluene-4''-sulfonyl)-oxazolidin-2'-yl>-ethanol

Cas No:143738-97-0

R&D Labs maybe for 143738-97-0

TIANJIN ZHONGXIN CHEMTECH CO.,LTD.

Contact:86-022-66880623

Address:FINANCIAL STREET WEST BLK 7, #308, NO.52 XINCHENG WEST ROAD, TEDA, TIANJIN, P.R.CHINA
WUHU HUAHAI BIOLOGY ENGINEERING CO LTD

Contact:+86-553-3836920

Address:7/F NO.82 LAODONG ROAD WUHU CHINA
Jiangxi Dongbang Pharmaceutical Co., Ltd.

Contact:+86-795-4433603, 4433388

Address:Fengxin Industrial Park, Fengxin County, Jiangxi Province, P.R.C
Hebei DaPeng Pharm & Chem Co., Ltd.

Contact:86-317-7298678,0576-88861898 88861908

Address:West Songmen Village, East Songmen Town, Wuqiao, Cangzhou, Hebei ,China
Jiaxing Carry Bio-Chem Technology Co.,Ltd

website:http://www.carrybiotech.com

Contact:0573-82788958

Address:Add.Fl 3th, Pharm Vally,Kaichuang Rd, Xiuzhou District, Jiaxing, Zhejiang,314031,China

Relevant to this article

Synthesis of ceramidated GLA-60 derivatives

Doi:10.1016/S0008-6215(02)00179-9
(2002)
The Absolute Stereochemistries of (+)-Toddalolactone and its Related Chiral Coumarins from Toddalia asiatica (L.) Lam. (T. aculeata Pers.) and their Optical Purities

Doi:10.1039/P19920001681
(1992)
Experimental and theoretical characterization of FSi(OCH₃)₂(OCH₂)^-: A gas phase fluoride-siloxirane adduct

Doi:10.1021/ja963382a
(1997)
The direct carboxylation of terminal alkynes with carbon dioxide

Doi:10.1039/c0gc00819b
(2011)
Synthesis of the first 2,3-dihydro-1,2,3-azadiphosphete complex

Doi:10.1039/b206233j
(2002)
Protecting group directed stereoselective reduction of an epi-inosose: Efficient synthesis of epi-inositol

Doi:10.1016/j.tetlet.2011.05.051
(2011)

Article Doi