Journal of the Chemical Society. Chemical communications p. 986 - 988 (1992)
Update date:2022-07-30
Topics:
Zhou, Zhang-Lin
Huang, Yao-Zeng
Shi, Li-Lan
Diisobutyltelluronium trimethylsilylpropynyl ylide, generated from 3-trimethylsilylprop-2-ynyldiisobutyltelluronium bromide with lithium 2,2,6,6-tetramethylpiperidide (LiTMP), reacts with carbonyl compounds to afford predominately cis-trimethylsilylethynyl epoxides in good to excellent yields.
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