Please do not adjust margins
ChemComm
Page 4 of 4
DOI: 10.1039/C5CC08794E
COMMUNICATION
Journal Name
independent reflections (Rint = 0.0284), 396 parameters, R1
0.0537 ( ≥ 2 )), wR2 = 0.1558; CCDC number 1407255.
=
I
σ(I
1 T. Sakakura, J.-C. Choi and H. Yasuda, Chem. Rev., 2007,
107, 2365.
2 For example, see: (
Fröhlich, S. Grimme, D. W. Stephan and G. Erker, Angew.
Chem., Int. Ed., 2009, 48, 6643; ( ) C. T. Saouma, C. C. Lu,
M. W. Day and J. C. Peters, Chem. Sci., 2013, , 4042; ( ) L.
Zhang, J. Cheng, B. Carry and Z. Hou, J. Am. Chem. Soc.,
2012, 134, 14314; ( ) Q. Liu, L. Wu, R. Jackstell and M.
Beller, Nat. Commun., 2015, , 5933.
a) C. M. Mömming, E. Otten, G. Kehr, R.
b
4
c
d
6
3 C. Martín, G. Fiorani and A. W. Kleij, ACS Catal., 2015,
1353.
5,
4 D. J. Darensbourg, Chem. Rev., 2007, 107, 2388.
5 Y.-M. Shen, W.-L. Duan and M. Shi, J. Org. Chem., 2003,
68, 1559.
6 A. Decortes, M. M. Belmonte, J. Benet-Buchholz and A. W.
Kleij, Chem. Commun., 2010, 46, 4580.
7 A. Decortes and A. W. Kleij, ChemCatChem, 2011, 3, 831.
8 C. J. Whiteoak, N. Kielland, V. Laserna, F. Castro-Gómez, E.
Martin, E. C. Escudero-Adán, C. Bo and A. W. Kleij, Chem.
Eur. J., 2014, 20, 2264.
9 W. Clegg, R. W. Harrington, M. North and R. Pasquale,
Chem. Eur. J., 2010, 16, 6828.
10 D. R. Moore, M. Cheng, E. B. Lobkovsky and G. W. Coates,
J. Am. Chem. Soc., 2003, 125, 11911.
11 K. Nakano, K. Nozaki and T. Hiyama, J. Am. Chem. Soc.,
2003, 125, 5501.
12 B. Y. Lee, H. Y. Kwon, S. Y. Lee, S. J. Na, S. Han, H. Yun,
H. Lee and Y.-W. Park, J. Am. Chem. Soc., 2005, 127, 3031.
13 F. Jutz, A. Buchard, M. R. Kember, S. B. Fredriksen and C.
K. Williams, J. Am. Chem. Soc., 2011, 133, 17395.
14 M. V. Escárcega-Bobadilla, M. M. Belmonte, E. Martin, E. C.
Escudero-Adán and A. W. Kleij, Chem. Eur. J., 2013, 19,
2641.
15 Y. Yang, Y. Hayashi, Y. Fujii, T. Nagano, Y. Kita, T.
Ohshima, J. Okuda and K. Mashima, Catal. Sci. Technol.,
2012, 2, 509.
16 W.-L. Tong, S.-M. Yiu and M. C. W. Chan, Inorg. Chem.,
2013, 52, 7114.
17 Z. Guo, S.-M. Yiu and M. C. W. Chan, Chem. Eur. J., 2013,
19, 8937.
18 A. M. Castilla, S. Curreli, E. C. Escudero-Adán, M. Martínez
Belmonte, J. Benet-Bunchholz and A. W. Kleij, Org. Lett.,
2009, 11, 5218.
19 S. J. Wezenberg, G. Salassa, E. C. Escudero-Adán, J. Benet-
Bunchholz and A. W. Kleij, Angew. Chem., Int. Ed., 2011, 50
,
713.
20 M. Martínez Belmonte, S. J. Wezenberg, R. M. Haak, D.
Anselmo, E. C. Escudero-Adan, J. Benet-Buchholz and A. W.
Kleij, Dalton Trans., 2010, 39, 4541.
21 The Al-[amino-tris(phenolate)] catalyst gave a TOF of 7600
h–1 (ref. 8; 0.0025 mol%, 10 bar
p
, 90
°
C, 2 h); higher
TOF values were reported at significantly lower catalyst
loadings. The [(Al-salen)2( -O)] catalyst was also tested, at
CO2
μ
0.0005 mol% loading under identical conditions, to yield a
TOF of 15000 h–1.
22 Reports of highly active Co- and Al-salen catalysts under
mild conditions: (
Tian, Y.-M. Wang, C.-X. Bai, H. Wang and R. Zhang, J. Am.
Chem. Soc., 2004, 126, 3732; ( ) W.-M. Ren, Y. Liu and X.-
a) X.-B. Lu, B. Liang, Y.-J. Zhang, Y.-Z.
b
B. Lu, J. Org. Chem., 2014, 79, 9771.
23 An additional mechanism invoking simultaneous epoxide and
iodide coordination at the Zn2 centers, leading to accelerated
ring-opening, should also be considered.
4 | J. Name., 2012, 00, 1-3
This journal is © The Royal Society of Chemistry 20xx
Please do not adjust margins