(2S,3S)-2,3-Epoxy-3-trimethylsilylpropanal as a New Conjunctive Reagent

DOI: 10.1016/S0040-4039(00)74683-1

Source and publish data:

Tetrahedron Letters p. 4179 - 4182 (1992)

Update date:2022-08-04

Topics:

Authors:

Urabe, Hirokazu

Matsuka, Tetsuji

Sato, Fumie

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Article abstract of DOI:10.1016/S0040-4039(00)74683-1

The title epoxy aldehyde (>98percent ee) has been prepared.Its reactions with nucleophiles afforded the corresponding adducts with a diastereoselectivity up to 86:14.Synthetic versatility of the chiral epoxy silane moiety makes this aldehyde a useful conjunctive reagent.

Full text of DOI:10.1016/S0040-4039(00)74683-1

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Product name:3-Hydroxy-3-((2S,3S)-3-trimethylsilanyl-oxiranyl)-propionic acid ethyl ester

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