Tetrahedron p. 2421 - 2428 (1996)
Update date:2022-07-30
Topics:
Vergne, Fabrice
Partogyan, Karolin
Aitken, David J.
Husson, Henri-Philippe
A new synthesis of trans-1,2-diaminocyclobutane 1 is described, in which the key feature is the novel stereoselective borane-induced reductive ring-expansion reaction of the cyclopropane-iminonitrile 2 to give the cyclobutane 4, This latter intermediate was also used to prepare a trans-fused rigid analogue of moclobemide.
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Doi:10.1021/ja00048a008
(1992)Doi:10.1002/chem.201202745
(2012)Doi:10.1517/13543776.2014.851670
(2014)Doi:10.1039/c3cc43092h
(2013)Doi:10.1016/j.ejmech.2013.03.050
(2013)Doi:10.1021/ja804412k
(2008)
