Tetrahedron Letters p. 4803 - 4806 (1992)
Update date:2022-09-26
Topics:
Al Dulayymi, Juma'a R.
Baird, Mark S.
Fitton, Helen L.
Reaction of 3-alkyl-1,2-dibromocyclopropenes with electron-rich or electron-poor alkenes in solution at 0 - 20°C leads to cyclopropanes apparently derived by stereoselective trapping of a single isomer of a vinylcarbene; in the absence of an alkene, the cyclopropenes rearrange to alknes.
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Doi:10.1021/ol4014238
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