Synthesis of N-Boc-Protected 1-Amino-3-alken-2-ols from Allylic Carbamates via Palladium(II)-Catalyzed Oxidative Cyclization

DOI: 10.1021/jo00049a001

Source and publish data:

Journal of Organic Chemistry p. 6083 - 6085 (1992)

Update date:2022-08-03

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Authors:

Benthem, Rolf A. T. M. van

Hiemstra, Henk

Speckamp, W. Nico

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Article abstract of DOI:10.1021/jo00049a001

Methyl glyoxylate adducts of N-Boc-protected allylic amines cyclize in the presence of catalytic Pd(OAc)2 and excess Cu(OAc)2 in DMSO to 5-(1-alkenyl)-2-(methyoxycarbonyl)oxazolidines.These heterocycles are readily converted to unsaturated.N-Boc-protected

Full text of DOI:10.1021/jo00049a001

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