A stereochemical study on the intramolecular hydrosilylation of α,β-unsaturated esters

DOI: 10.1016/S0040-4039(00)61182-6

Source and publish data:

Tetrahedron Letters p. 5037 - 5040 (1992)

Update date:2022-08-04

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Authors:

Denmark, Scott E.

Forbes, David C.

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Article abstract of DOI:10.1016/S0040-4039(00)61182-6

The intramolecular hydrosilylation of several 3-methyl-4-siloxy-2-butenoates afforded cis disubstituted lactones after desilylation. The diastereoinduction was sensitive to the bulk of the allylic substituent, but not to the groups on silicon. The origin

Full text of DOI:10.1016/S0040-4039(00)61182-6

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