Journal of Fluorine Chemistry p. 239 - 247 (1992)
Update date:2022-09-26
Topics:
Hedhli, A.
Chaabouni, M. M.
Baklouti, A.
The simple 2-fluorotosylates eliminate p-toluenesulphonic acid (HOTs) in baisc media, the tosyl group being substituted by the action of a nucleophile.In contrast the F-alkylated homologous RF-CHOTs-CH2F undergo elimination of HF in the presence of a donor reagent leading to the 1-F-alkylvinyl p-toluenesulphonates RF-COTs=CH2.Depending on the reaction conditions and the nature of the base, these vinyl tosylates can react firther to give other F-alkylated products (F-alkylmethylketones, 1-hydroxy F-alkanes, 1-F-alkyl ethanols and F-alkylmethylhydrazones).
View MoreContact:0833-5590788/5590338/5590055
Address:Victory in the town of Red Star Village,Mount Emei City,industrial concentration area storage processing logistics parkpark
Beijing Wisdom Chemicals Co., Ltd.
Contact:+86-10-52350335
Address:F2, BLDG 19, Liando Valley U, Majuqiao, Tongzhou District, Beijing, China
Anhui Dexinjia Biopharm Co., Ltd
Contact:+86-531-82375818
Address:9 Hexie Road, kaifaqu, Taihe
Contact:86+21-56421993
Address:3F,BUILDING 10,NO.2889 JINKE ROAD, SHANGHAI.
Zhenjiang Haitong Chemical Industry Co., Ltd.
Contact:+86 (511) 8448-0369
Address:Baoyan Town, Dantu District, Zhenjiang City, Jiangsu, China
Doi:10.1055/s-0032-1316909
(2013)Doi:10.1021/ic401450u
(2013)Doi:10.1021/ol401925u
(2013)Doi:10.1055/s-0033-1338848
(2013)Doi:10.1246/bcsj.20130004
(2013)Doi:10.1039/c3nj00644a
(2013)