Dienophilic Activity of Vinyldichloroboranes and their Use as Partners in Diels-Alder-Reductive Alkylation of Azides in One-pot Reaction

DOI: 10.1039/c39920001105

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Journal of the Chemical Society. Chemical communications p. 1105 - 1107 (1992)

Update date:2022-08-05

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Authors:

Noiret, Nicolas

Youssofi, Abdullah

Carboni, Bertrand

Vaultier, Michel

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Article abstract of DOI:10.1039/c39920001105

Vinyldichloroboranes react with 1,3-dienes and the sequence Diels-Alder cycloaddition-reductive alkylation of benzyl azide leads directly to secondary amines, therefore, showing that vinyldichloroboranes behave as synthetic equivalents of secondary enamines of defined stereochemistry.

Full text of DOI:10.1039/c39920001105

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