Silicon-directed Bamford-Stevens Reaction of β-Trimethylsilyl N-Aziridinylimines

DOI: 10.1039/c39920001184

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1184 - 1185 (1992)

Update date:2022-08-04

Topics:

Authors:

Sarkar, Tarun K.

Ghorai, Binay K.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920001184

The Me3Si group in β-trimethylsilyl N-aziridinylimines is able to direct the Bamford-Stevens reaction with or without rhodium acetate as catalyst to give allylic silanes as major or exclusive products.

Full text of DOI:10.1039/c39920001184

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1-Aziridinamine, 2-phenyl-N-[1-[2-(trimethylsilyl)ethyl]tridecylidene]-, (E)-

Cas No:144487-94-5

R&D Labs maybe for 144487-94-5

Suzhou CarbonWell Pharma-Tech Co., Ltd

Contact:Tel: + 86 (0)512-8898-1216; + 86-18606258602

Address:2358 Changan Road, Wujiang Scientific Innovation Park, Wujiang, Jiangsu Province, P. R. China 215200
Beijing Tianjia Chemical Science & Technology Co.,Ltd

Contact:86-0550-2392698

Address:No.388, Shiliang Road (East),
WEIFANG RICHEM INTERNATIONAL LTD

Contact:86-536-2222176

Address:weifang,shandong
SJZ THLD IMP & EXP CO LTD

website:http://www.truewingroup.com

Contact:86-311-66699812

Address:NO.600 ZHONGSHAN EAST ROAD SHIJIAZHUANG
Nanjing Chemipioneer Pharma&Tech Co.,Ltd

website:http://www.chemipioneer.com.cn

Contact:+86-25-52685700

Address:Room 305，A Block，Biological-Medicine Building，Business Start-up Center，Xin-ke 1st Road, High-tech development zone，Nanjing city，Jiangsu Province, China

Relevant to this article

Catalytic olefination reaction. Synthesis of fluorinated ethers and thioethers

Doi:10.1007/s11172-012-0187-2
(2012)
An Efficient Strategy for the Synthesis of Naphtho[2,3- b ][1,6]naphthyridines Promoted by Acetic Acid

Doi:10.1055/a-1479-4420
(2021)
An efficient strategy for protecting dihydroxyl groups of catechols

Doi:10.1055/s-0032-1318332
(2013)
One-Pot cascade hydration-asymmetric transfer hydrogenation as a practical strategy to construct chiral β-adrenergic receptor blockers

Doi:10.1002/cctc.201500409
(2015)
Asymmetric Hydrophosphination of Heterobicyclic Alkenes: Facile Access to Phosphine Ligands for Asymmetric Catalysis

Doi:10.1021/acscatal.8b04787
(2019)
Zirconium hydrazides as metallanitrene synthons: Release of molecular N₂ from a hydrazinediido complex induced by oxidative N-N bond cleavage

Doi:10.1021/om400337g
(2013)

Article Doi