Silicon-directed Bamford-Stevens Reaction of β-Trimethylsilyl N-Aziridinylimines

DOI: 10.1039/c39920001184

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1184 - 1185 (1992)

Update date:2022-08-04

Topics:

Authors:

Sarkar, Tarun K.

Ghorai, Binay K.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920001184

The Me3Si group in β-trimethylsilyl N-aziridinylimines is able to direct the Bamford-Stevens reaction with or without rhodium acetate as catalyst to give allylic silanes as major or exclusive products.

Full text of DOI:10.1039/c39920001184

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1-Aziridinamine, 2-phenyl-N-[1-[2-(trimethylsilyl)ethyl]tridecylidene]-, (E)-

Cas No:144487-94-5

R&D Labs maybe for 144487-94-5

SHANGHAI BIOSUNDRUG CO.,LTD.

Contact:86-21-34622192，13917187091，21-34622765

Address:No. 500 Caobao Road Shanghai P.R China
PINGYUAN SIHUAN PHARMACEUTICAL CO., LTD

Contact:+86-531-55696072

Address:#2766,yinxiu Road, Economic Development Zone, Pingyuan Country, Shandong Province, China.
Shangyu Sanhechemicals Co.,LTD.

Contact:86-0571-56696839

Address:Num.2952,Nanhuan Road,Binjiang District,Hangzhou,China
Beijing ZhongDaXinHe Chemical Product Co.,Ltd(expird)

Contact:010-52876516

Address:tongzhoubeiyuan
Hubei Danao Pharmaceutical Co.,Ltd.

website:http://www.danaopharm.com

Contact:+86-719-5251167

Address:Fandan Road,Danjiangkou,Hubei

Relevant to this article

Catalytic olefination reaction. Synthesis of fluorinated ethers and thioethers

Doi:10.1007/s11172-012-0187-2
(2012)
An Efficient Strategy for the Synthesis of Naphtho[2,3- b ][1,6]naphthyridines Promoted by Acetic Acid

Doi:10.1055/a-1479-4420
(2021)
An efficient strategy for protecting dihydroxyl groups of catechols

Doi:10.1055/s-0032-1318332
(2013)
One-Pot cascade hydration-asymmetric transfer hydrogenation as a practical strategy to construct chiral β-adrenergic receptor blockers

Doi:10.1002/cctc.201500409
(2015)
Asymmetric Hydrophosphination of Heterobicyclic Alkenes: Facile Access to Phosphine Ligands for Asymmetric Catalysis

Doi:10.1021/acscatal.8b04787
(2019)
Zirconium hydrazides as metallanitrene synthons: Release of molecular N₂ from a hydrazinediido complex induced by oxidative N-N bond cleavage

Doi:10.1021/om400337g
(2013)

Article Doi