Novel stannylenes stabilized with diethylenetriamido and related amido ligands: Synthesis, structure, and chemical properties

Article abstract of DOI:10.1002/zaac.201200552

Complexes of divalent tin 7-12 with diethylenetriamines 1-3 and related ligands 4-6 were prepared from Lappert's stannylene, Sn[N(SiMe₃) ₂]₂, and the corresponding ligands. Reactivity of the stannylenes in insertion, oxida

Full text of DOI:10.1002/zaac.201200552

Z. Anorg. Allg. Chem. 2013 · © WILEY-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, 2013 · ISSN 0044–2313
SUPPORTING INFORMATION
Title: Novel Stannylenes Stabilized with Diethylenetriamido and Related Amido Ligands: Synthesis,
Structure, and Chemical Properties
Author(s): M. Huang, M. M. Kireenko, E. K. Lermontova, A. V. Churakov, Yu. F. Oprunenko, K. V.
Zaitsev,* D. Sorokin, K. Harms, J. Sundermeyer,* G. S. Zaitseva, S. S. Karlov
Ref. No.: Z201200552

Z. Anorg. Allg. Chem. 2013 · © WILEY-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim,
2013 · ISSN 0044–2313
SUPPORTING INFORMATION
Title: Novel Stannylenes Stabilized with Diethylenetriamido and Related Amido Ligands:
Synthesis, Structure and Chemical Properties
Author(s): Mengmeng Huang, Marina M. Kireenko, El’mira Kh. Lermontova, Andrei V.
Churakov, Yuri F. Oprunenko, Kirill V. Zaitsev*, Jörg Sundermeyer**, Galina S. Zaitseva and
Sergey S. Karlov
Ref. No.: zaac.201200552
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Figure S1. 19F NMR spectrum (CDCl3, 298 K) of complex 8.
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Figure S2. 119Sn NMR spectrum (CDCl3, 298 K) of 8.