New synthesis and reactions of [Sm(OTf)2(DME)2], a salt-free samarium(II) triflate

DOI: 10.1016/S0040-4039(99)00417-7

Source and publish data:

Tetrahedron Letters p. 3161 - 3164 (1999)

Update date:2022-09-26

Topics:

Authors:

Collin, Jacqueline

Giuseppone, Nicolas

Machrouhi, Fouzia

Namy, Jean-Louis

Nief, Francois

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Article abstract of DOI:10.1016/S0040-4039(99)00417-7

A new, simple and high-yield synthesis of a salt-free samarium(II) triflate, [Sm(OTf)₂(DME)₂] is described. In stoichiometric amounts this derivative mediates typical samarium (II) coupling reactions such as pinacolisation, dimerisat

Full text of DOI:10.1016/S0040-4039(99)00417-7

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