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Copper(I) and Silver(I) Homometallic Complexes of New Bis(2,2'-bipyridine) Ligands

DOI: 10.1039/DT9920002667

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2667 - 2674 (1992)

Update date:2022-09-26

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Authors:

Beer, Paul D.Beer, Paul D.

Wheeler, John W.Wheeler, John W.

Moore, Christopher P.Moore, Christopher P.

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Article abstract of DOI:10.1039/DT9920002667

New ligand systems containing two 2,2'-bipyridin-6-ylmethyl moieties linked via 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane, 1,4,10,13-tetrathia-7,16-diazacyclooctadecane, 4,4'-bipyridinediium, N,N',N''-tritosyldiethylenetriamine and toluene-p-sulfonamide spacer units have been prepared.A variety of homometallic copper(I) complexes have been isolated and fast atome bombardment mass spectrometry investigations suggest most of the complexes to be of general formula 2.Solution 1H NMR spectra of these species imply the existence of additional complex components of 1:1 L:copper(I) ratio.A variety of mono- and bi-metallic silver(I) complexes were also isolated with these ligands.

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Product name:N,N''-bis(2,2'-bipyridin-6-ylmethyl)-N,,N',N''-tri(toluene-p-sulfonyl)diethylenetriamine

Cas No:144809-32-5

144809-32-5

R&D Labs maybe for 144809-32-5

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