Bulletin of the Chemical Society of Japan p. 2456 - 2464 (1992)
Update date:2022-08-04
Topics:
Wada, Eiji
Funakoshi, Junji
Kanemasa, Shuji
The reactions of 2-oxo-3-alkenylphosphonates with carbonyl-stabilized carbanions directly lead to 2-cyclohexen-1-ones through a sequence of Michael reaction and intramolecular Horner-Emmons olefination.On the other hand, the Lewis acid-mediated reactions with silyl enol ethers produce 1,5-diketones as Michael adducts, which then undergo cyclization on treatment with sodium hydride or triethylamine/zinc (II) bromide to afford 2-cyclohexen-1-ones or 2-phosphinyl-2-cyclohexen-1-ones, respectively.
View MoreContact:+31-24-3886056
Address:Binderskampweg 29 Unit 36
Rudong Zhenfeng Yiyang Chemical Co., Ltd.
Contact:0513-84573047
Address:South Fengli Town, Rudong County, Jiangsu Province, China
Nanjing Chemzam Pharmtech Co., Ltd.
Contact:+86-25-86462165,+86-13915979898
Address:C5-1,6 Maiyue Road,Maigaoqiao,Nanjing,Jiangsu,China
Chengdu NoVi Biotechnology Co., Ltd.(expird)
Contact:13551243286/028-81458053
Address:NO.168-1-224 JULONG ROAD WUHOU DISTRICT, CHENGDU CITY,SICHUAN PROVINCE
Dongguan Albiya Energy Science and Technology Co.,Ltd
Contact:+86-769-22181286
Address:Huanan Industial Park, Dongguan,China
Doi:10.1021/om400630q
(2013)Doi:10.1021/cs500874z
(2014)Doi:10.1016/j.tetlet.2013.11.041
(2014)Doi:10.1002/ardp.19923250909
(1992)Doi:10.1016/S0040-4020(01)97605-7
(1964)Doi:10.1021/acs.jmedchem.9b01526
(2020)