Chemistry of novel compounds with multifunctional carbon structure. 8. Application of the α-cyano-α-fluorophenylacetic acid (CFPA) method to the enantiomeric excess determination of some hindered alcohols in asymmetric and natural product syntheses

DOI: 10.1016/S0040-4020(01)80542-1

Source and publish data:

Tetrahedron p. 1861 - 1870 (1993)

Update date:2022-08-04

Topics: Asymmetric synthesis Natural Product Synthesis

Authors:

Takeuchi

Itoh Itoh

Kawahara

Koizumi Koizumi

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Article abstract of DOI:10.1016/S0040-4020(01)80542-1

The reaction of CFPA chloride (2b) with pinacolyl alcohol was found to proceed more than 500 times faster than that of MTPA chloride (1b) suggesting that the CFPA method induces potentially much less kinetic resolution than the widely used MTPA method in

Full text of DOI:10.1016/S0040-4020(01)80542-1

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Product name:2-octyl α-cyano-α-fluorophenylacetate

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