Journal of the Chemical Society. Chemical communications p. 1489 - 1490 (1992)
Update date:2022-08-05
Topics:
Clive, Derrick L. J.
Tao, Yong
Khodabocus, Ahmad
Wu, Yong-Jin
Angoh, A. Gaoetan
et al.
(+/-)-Fredericamycin A 1 is synthesized using 5-exo-digonal radical closure of selenide 15 (Scheme 2), and an unusual procedure for both selective demethylation of the advanced intermediate 22 and adjustment of the stereochemistry in the pentadienyl side
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