Advanced Synthesis and Catalysis p. 667 - 672 (2013)
Update date:2022-07-30
Topics:
Sharma, Satyasheel
Kim, Aejin
Park, Eonjeong
Park, Jihye
Kim, Minyoung
Kwak, Jong Hwan
Lee, Sang Hwi
Jung, Young Hoon
Kim, In Su
A palladium-catalyzed oxidative acylation of O-phenyl carbamates with α-oxocarboxylic acids via selective aromatic C-H bond activation is described. This protocol represents the first ortho-acylation of phenol derivatives, and a catalytic amount of triflic acid additive is crucial for this transformation. Copyright
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