Versatile Behavior of O-Stannylated D-Glucal Towards Halogens

DOI: 10.1016/0040-4039(92)88055-A

Source and publish data:

Tetrahedron Letters p. 221 - 224 (1992)

Update date:2022-07-30

Topics:

Authors:

Czernecki, Stanislas

Leteux, Christine

Veyrieres, Alain

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Article abstract of DOI:10.1016/0040-4039(92)88055-A

O-Tributylstannyl-D-glucal undergoes allylic oxidation when treated with N-iodosuccinimide (NIS) in benzene, whereas oxidative 1,6-halocyclization occurs with NIS in acetonitrile or molecular halogens in various solvents.Key Words: tributyltin ethers; D-glucal; allylic oxidation; halocylization; <3.2.1>bicyclic synthons

Full text of DOI:10.1016/0040-4039(92)88055-A

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