Mild Generation of Alkylidenecarbenes from α-Mesyloxynitriles of Sugars. Application to the Synthesis of Branched-chain Sugars

DOI: 10.1039/c39920001403

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Journal of the Chemical Society. Chemical communications p. 1403 - 1404 (1992)

Update date:2022-08-04

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Authors:

Perez-Perez, Maria-Jesus

Camarasa, Maria Jose

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Article abstract of DOI:10.1039/c39920001403

Treatment of O-mesylcyanohydrins of furanos-3-ulose with sodium azide vinylazidoderivatives; the intermediary of an alkylidenecarbene is proposed, and reactions to trap such an intermediate are described.

Full text of DOI:10.1039/c39920001403

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