
Journal of Organic Chemistry p. 832 - 839 (1993)
Update date:2022-08-04
Topics:
Wovkulich, P. M.
Shankaran, K.
Kiegiel, J.
Uskokovic, M. R.
The total synthesis of the HMG-CoA synthase inhibitor 1233A (1), starting from either (R)-pulegone (6) or diketo ester 12, is described.The key transformations included the diastereoselective <2,3> rearrangements of allylic ethers 9 and 19 to alcohols 10
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