Reaction of a Serine-derived Organozinc Reagent with Chloroformates and Ethyl Oxalyl Chloride Under Palladium Catalysis. Preparation of Protected (2S,6S)-4-Oxo-2,6-diaminopimelic Acid and (2S)-4-Oxoglutamic Acid

DOI: 10.1039/c39920001587

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1587 - 1589 (1992)

Update date:2022-08-04

Topics: Palladium Catalysis Glutamic acid Organozinc reagent Chloroformates

Authors:

Jackson, Richard F. W.

Wishart, Neil

Wythes, Martin J.

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Article abstract of DOI:10.1039/c39920001587

Organozinc reagent 1 reacts with phenyl chloroformate under palladium catalysis to give the protected 4-oxo-2,6-diaminopimelic acid derivative 3, derived by formal displacement of both chloride and phenoxide; the symmetrical ketone 3, together with protec

Full text of DOI:10.1039/c39920001587

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