Photoinduced Electron-transfer Reaction of 7-Benzhydrylidenenorbornene: Chemical Capture of a Radical Cation Intermediate with Nonclassical Cation Character

DOI: 10.1039/c39920001544

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1544 - 1545 (1992)

Update date:2022-09-26

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Authors:

Hirano, Takashi

Shiina, Satoshi

Ohashi, Mamoru

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Article abstract of DOI:10.1039/c39920001544

A photoinduced electron-transfer reaction of benzhydrylidenenorbornene 1 as an electron donor gives the radical cation, which could be captured chemically by methanol or by the intramolecular hydroxy group, indicating the existence of a strong homoconjugative interaction between the exocyclic double bond and the C(2)-C(3) double bond.

Full text of DOI:10.1039/c39920001544

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