The preparation of intermediates for the synthesis of 1D-myo-inositol 1,4,5-triphosphate, a second messenger for signal transduction in cells

Article abstract of DOI:10.1016/0008-6215(92)85035-X

Racemic 1,2,4-tri-O-benzyl-5,6-O-isopropylidene-myo-inositol was prepared by a new route involving crotyl (but-2-enyl) ethers and converted into (-)-ω-camphanates to give the pure crystalline 1L-diastereoisomer and the chirally impure, syrupy 1D-diastereo