Journal of Fluorine Chemistry p. 225 - 232 (1992)
Update date:2022-09-26
Topics:
Miyamoto, Kenji
Tsuchiya, Shigeo
Ohta, Hiromichi
α-Methyl-α-(trifluoromethylphenyl)malonic acids have been incubated with Alcaligenes bronchisepticus to afford optically active α-arylpropionic acids.Generally, the chemical and optical yields of the reaction products were higher when the substituents on the aromatic ring were strongly electron-withdrawing.Decarboxylation of α-fluoro-α-phenylmalonic acid with the aid of the same bacterium afforded optically active α-fluoro-α-phenylacetic acid.
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