Synthesis of Vinylcyclopropanes by Intramolecular Epoxide Ring Opening. Application for an Enantioselective Synthesis of Dictyopterene A

DOI: 10.1021/jo00055a014

Source and publish data:

Journal of Organic Chemistry p. 626 - 632 (1993)

Update date:2022-08-02

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Authors:

Narjes, Frank

Bolte, Oliver

Icheln, Detlef

Koenig, Wilfried A.

Schaumann, Ernst

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Article abstract of DOI:10.1021/jo00055a014

The reaction of functionalized oxiranes 1 with the sulfur- or silicon-stabilized anions 2 provides β-heteroatom-substituted γ,δ-unsaturated epoxides 5 with, for 5e,f, a trans C=C moiety.A cis compound 9 is obtained using acetylide anion 2c via 7 and subse

Full text of DOI:10.1021/jo00055a014

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