Chemistry, kinetics, and spectroscopy of highly hindered diarylcarbenes. The case of decachlorodiphenylcarbene

DOI: 10.1021/ja00057a010

Source and publish data:

Journal of the American Chemical Society p. 1285 - 1289 (1993)

Update date:2022-08-02

Topics: Steric hindrance Kinetics Photolysis UV-Vis Spectroscopy Substituent Effects Spectroscopy Computational Chemistry Laser Flash Photolysis Activation Energy Triplet State EPR Spectroscopy Transient absorption spectroscopy Reaction intermediate Singlet state

Authors:

Tomioka, Hideo

Hirai, Katsuyuki

Nakayama, Takehito

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Article abstract of DOI:10.1021/ja00057a010

Bis(pentachlorophenyl)diazomethane (1a) was prepared, and reactivities of perchlorodiphenylcarbene (2a) generated by photolysis of la were investigated not only in terms of product analysis but also by using flash photolysis techniques. Although the major

Full text of DOI:10.1021/ja00057a010

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