Chemistry, kinetics, and spectroscopy of highly hindered diarylcarbenes. The case of decachlorodiphenylcarbene

DOI: 10.1021/ja00057a010

Source and publish data:

Journal of the American Chemical Society p. 1285 - 1289 (1993)

Update date:2022-08-02

Topics: Steric hindrance Kinetics Photolysis UV-Vis Spectroscopy Substituent Effects Spectroscopy Computational Chemistry Laser Flash Photolysis Activation Energy Triplet State EPR Spectroscopy Transient absorption spectroscopy Reaction intermediate Singlet state

Authors:

Tomioka, Hideo

Hirai, Katsuyuki

Nakayama, Takehito

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00057a010

Bis(pentachlorophenyl)diazomethane (1a) was prepared, and reactivities of perchlorodiphenylcarbene (2a) generated by photolysis of la were investigated not only in terms of product analysis but also by using flash photolysis techniques. Although the major

Full text of DOI:10.1021/ja00057a010

Products guided by the article

Product name:ethyl N-carbamate

Cas No:146475-43-6

R&D Labs maybe for 146475-43-6

Shenzhen Sunrising Industry Co., ltd.

Contact:+86 755 86571158 / 86571159 / 86571160

Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
HEBEI BRANT PHARMACEUTICAL

Contact:+86-0311-84455288-844

Address:Mayu Industrial Park, Jinzhou, Hebei, China.
TLS PHARMACEUTICAL CO.,LTD

Contact:0833-5590788/5590338/5590055

Address:Victory in the town of Red Star Village,Mount Emei City,industrial concentration area storage processing logistics parkpark
Beijing Tianjia Chemical Science & Technology Co.,Ltd

Contact:86-0550-2392698

Address:No.388, Shiliang Road (East),
Chengdu ZY Biochemical Technology Co., LTD

Contact:0086-28-88680086

Address:170 Qingpu Road, Shouan Town, Pujiang County

Relevant to this article

Approaches towards indolic analogues of cephalotaxine via a spiro-cyclohexene strategy

Doi:10.1016/0040-4039(93)85103-4
(1993)
Copper-mediated cross-coupling of H-phosphonates with vinyliodonium salts: A novel very mild synthesis of 2-arylvinylphosphonates

Doi:10.1021/ol047516y
(2005)
A general metal-free approach for the stereoselective synthesis of C-glycals from unactivated alkynes

Doi:10.3762/bjoc.10.277
(2014)
On DABAL-Me₃ promoted formation of amides

Doi:10.1016/j.tet.2013.08.062
(2013)
New Tetracyclic Derivatives of Imidazo<1,5-a><1,4>benzodiazepines and of Imidazo<1,5-a>thieno<3,2-f>diazepines

Doi:10.3987/COM-94-S(B)61
(1994)
Etude du transfert monoelectronique entre des germylanions et des piegeurs de spin dia et paramagnetiques

Doi:10.1016/0022-328X(93)80008-Y
(1993)

Article Doi