Tetrahedron p. 9901 - 9916 (1992)
Update date:2022-07-30
Topics:
Van Der Louw
Van Der Baan
Out
De Kanter
Bickelhaupt
Klumpp
Addition of 2-(chloromagnesiomethyl)-2-propenyl ethers 1a and 1b to epoxides 3 affords ring opening products 6 or 7 which are converted by Pd(0) to 3-methylenetetrahydropyrans 9. Cyclization of the addition products is best effected by a catalyst system generated in situ from Pd(OAc)2 and (i-PrO)3P.
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Doi:10.1039/c39910001054
(1991)Doi:10.1016/S0040-4039(00)60858-4
(1992)Doi:10.1002/hlca.19920750805
(1992)Doi:10.1021/ol402279h
(2013)Doi:10.1002/jhet.5570290704
(1992)Doi:10.1071/CH13227
(2013)
