Phytochemistry p. 4259 - 4262 (1992)
Update date:2022-08-05
Topics:
Appendino, Giovanni
Lusso, Patrizia
Gariboldi, Pierluigi
Bombardelli, Ezio
Gabetta, Bruno
A collection of yew needles afforded a taxane diester characterized by an additional bond between C-3 and C-11.The structure was elucidated by spectral methods, and further confirmed by synthesis from a known taxane derivative.A general procedure for the photocyclization of taxicins is reported. Key words: Taxus baccata; Taxaceae; diterpenoids; 5-cinnamoyl-10-acetylphototaxicin; taxicins.
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