Sterically Hindered Organotin Compounds. Part 3. The Reaction Between Di-tert-butyltin Oxide and Organoboronic Acids

DOI: 10.1039/DT9920003503

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3503 - 3510 (1992)

Update date:2022-07-29

Topics:

Authors:

Brown, Paul

Mahon, Mary F.

Molloy, Kieran C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9920003503

The reaction between (Bu^t2SnO)3 and BR(OH)2 has been investigated and found to yield two classes of product.The first is a boron-rich species, cyclo-Bu^t2SnO(RBO)2, which exists alongside its acyclic hydrolysis product SnBu^t22.The second product, which is tin-rich, SnBu^t2(OH)2<(Bu^t2SnO)2OBR>2, can be formulated as cyclo-RBO(Bu^t2SnO)2 chelated across one Sn-O-Sn unit by a molecule of SnBu^t2(OH)2.The crystal and molecular structures of SnBu^t22 and SnBu^t2(OH)2<(Bu^t2SnO)2OBC6H2Me3-2,4,6>2*2MeCN have been determined.

Full text of DOI:10.1039/DT9920003503

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2,2-di-tert-butyl-4,6-dimesityl-1,3,5-trioxa-2-stannadiborinane

Cas No:146645-27-4

R&D Labs maybe for 146645-27-4

Zhengzhou HQ Material Co.,Ltd

Contact:+86-371-67759225

Address:No.32, Jinsuo Road, High-tech Zone
ClickChem Technology Co., Limited

Contact:+86-0310-6519966/0531-52893837

Address:No.750 Shunhua Road, High-Tech Zone, Jinan city, Shandong China
Nanjing Norris Pharm Technology Co., Ltd.

Contact:+86-13901585132

Address:2 Qiande Road, Jiangning sciencepark Hi-Tech Zone, Nanjing, P.R.China
Hubei anhuang chemical Co.Ltd

Contact:

Address:308# dongwu avenue dongxihu district wuhan city
Beijing Green Guardee Technology CO,.LTD

Contact:+86-10-69706062

Address:F2 BLdj,5 No.37 Chaoqian Road

Relevant to this article

Reductive elimination of glycosyl phenyl sulfones by SmI₂-HMPA: A convenient synthesis of substituted pyranoid glycals

Doi:10.1016/S0040-4039(00)74718-6
(1992)
A general oxindole synthesis

Doi:10.1055/s-1993-25790
(1993)
γ-Pyrone compounds. IV: Synthesis and antiplatelet effects of mono- and dioxygenated xanthones and xanthonoxypropanolamine

Doi:10.1002/jps.2600820103
(1993)
Di- and polynuclear silver(I) saccharinate complexes of tertiary diphosphane ligands: Synthesis, structures, in vitro DNA binding, and antibacterial and anticancer properties

Doi:10.1007/s00775-013-1052-y
(2014)
DNA fastening and ripping actions of novel Knoevenagel condensed dicarboxylic acid complexes in antitumor journey

Doi:10.1016/j.ejmech.2014.04.032
(2014)
9-membered carbocycle formation: Development of distinct friedel-crafts cyclizations and application to a scalable total synthesis of (±)-caraphenol A

Doi:10.1002/anie.201311299
(2014)

Article Doi