The diastereoselective synthesis of (+)-actinobolin from D-glucose

DOI: 10.1016/0040-4039(93)85088-E

Source and publish data:

Tetrahedron Letters p. 407 - 410 (1993)

Update date:2022-07-29

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Authors:

Ward Ward

Kaller Kaller

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Article abstract of DOI:10.1016/0040-4039(93)85088-E

The carbocyclic ring of actinobolin was constructed by a [3 + 3] annulation of a D-galactosamine derivative with 3-phenylthio-2-(trimethylsilylmethyl)propene. Formation of the lactone and acylation with L-alanine according to literature precedent gave (+)

Full text of DOI:10.1016/0040-4039(93)85088-E

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