Synthesis of pyrrolizidine alkaloids via rhodium-catalyzed silylformylation and amidocarbonylation

DOI: 10.1016/S0040-4039(00)77453-3

Source and publish data:

Tetrahedron Letters p. 915 - 918 (1993)

Update date:2022-08-05

Topics:

Authors:

Eguchi Eguchi

Zeng Zeng

Korda Korda

Ojima Ojima

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Article abstract of DOI:10.1016/S0040-4039(00)77453-3

Rhodium-catalyzed silylformylation and amidocarbonylation are applied to the syntheses of pyrrolizidine alkaloids (±)-isoretronecanol and (±)-trachelanthamidine, from 5-ethyl-2-pyrrolidinone.

Full text of DOI:10.1016/S0040-4039(00)77453-3

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Product name:(Z)-5-<(2-dimethylphenylsilyl-1-formyl)ethenyl>pyrrolidinone

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