Controlled Reaction of Molecular Oxygen with to form the Mixed Phosphine-Phosphine Oxide Complex and the Bis(phosphine oxide) Complex

DOI: 10.1039/DT9930003373

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3373 - 3378 (1993)

Update date:2022-08-03

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Authors:

Godfrey, Stephen M.

McAuliffe, Charles A.

Ndifon, Peter T.

Pritchard, Robin G.

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Article abstract of DOI:10.1039/DT9930003373

When a preformed solution of in pentane at -40 deg C under argon was allowed to warm to room temperature, specific oxidation of one phosphine occurred and an almost quantitative yield of the mixed phosphine-phosphine oxide complex was obtained; when the same procedure is followed under dry dioxygen the oxidation of both phosphines occurs and is obtained in almost quantitative yield.X-Ray crystallography showed both of these complexes to be pseudo-tetrahedral monomers, and represents the first example of a mixed phosphine-phosphine oxide complex of manganese to be reported.

Full text of DOI:10.1039/DT9930003373

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