Chemistry Letters p. 287 - 290 (1993)
Update date:2022-08-03
Topics:
Chen, Feng Qi
Hirano, Takashi
Ohashi, Mamoru
Nakayama, Hitoshi
Oda, Kazuaki
Machida, Minoru
A photoreactive analogue of coelenteramide (light emitting species in aequorin bioluminescence) has been synthesized for photoaffinity labeling studies of aequorin.Photolysis of this compound in methanol gave a formal OH insertion product in 62percent yield without damage of the main skeleton of coelenteramide, indicating a potential use for mapping the coelenterazine binding site in aequorin.
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Doi:10.1021/om00028a032
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