The role of torsional isomers of planarly chiral nonbridged bis(indenyl)metal type complexes in stereoselective propene polymerization

DOI: 10.1021/ja00064a022

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Journal of the American Chemical Society p. 4590 - 4601 (1993)

Update date:2022-08-03

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Authors:

Erker, Gerhard

Aulbach, Michael

Knickmeier, Markus

Wingbermühle, Doris

Krüger, Carl

Nolte, Matthias

Werner, Stefan

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Article abstract of DOI:10.1021/ja00064a022

Reaction of enantiomerically pure (l-neomenthylindenyl)lithium with ZrCl₄(THF)₂ gave the three diastereomeric bis(1-neomenthylindenyl)zirconium dichloride complexes 4a-A, -B, and -C, in a 93:2:5 ratio. Similarly, a 82:7:11 mixture of

Full text of DOI:10.1021/ja00064a022

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