Journal of Organometallic Chemistry p. 29 - 35 (1993)
Update date:2022-08-05
Topics:
Eibl, M.
Katzenbeisser, U.
Hengge, E.
1,3,5-Trichlorononamethylcyclohexasilane is the first trifunctional cyclohexasilane to be reported and is produced by the reaction of dodecamethylcyclohexasilane with SbCl5 beside the mono- and 1,3- and 1,4- dichlorinated methylcyclohexasilanes.Starting from this trichloro-compound, Ph-, Br-, F-, H-, and CF3SO3-derivatives were prepared and characterized by NMR, and the structure of the phenyl derivative was determined by X-ray diffraction.Different stereoisomers were formed as can be seen from detailed NMR investigation of the fluorine derivative.
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Doi:10.1002/adsc.202001269
(2021)Doi:10.1016/0040-4039(93)85021-N
(1993)Doi:10.1021/ja00099a022
(1994)Doi:10.1246/bcsj.66.841
(1993)Doi:10.1016/j.ejmech.2013.08.002
(2013)Doi:10.1016/S0022-1139(00)80418-2
(1993)
